Adiabatic Expansion: Cooling Without Losing Heat
1 · Predict
A gas expands quickly, with no time to exchange heat with its surroundings (adiabatic). Does the gas's temperature change even though no heat enters or leaves?
- The gas cools down — it does work on its surroundings using its own internal energy.
- The temperature stays the same, since no heat is exchanged.
- The gas heats up as it expands.
2 · Set Up
- Open the adiabatic-expansion preset and press Reset. 1 mol of diatomic nitrogen (f = 5) starts at 0.0249 m³, 300 K.
- Enable the final-temperature readout on the chamber.
- Set the target (final) volume for each trial, and record the final temperature and the work done.
3 · Collect Data
| Final volume V₂ (m³) | Work done by gas W_gas (J) | Final temperature T₂ (K) |
|---|---|---|
| 0.0374139 | ||
| 0.0498852 | ||
| 0.062356499999999995 |
Plot final temperature T₂ (y-axis) against final volume V₂ (x-axis) for your three trials. Does the line curve downward?
4 · Analyze
- For one trial, compute T₂ = T₁·(V₁/V₂)^(γ−1) using γ = (f+2)/f = 1.4, T₁ = 300 K, V₁ = 0.0249 m³. Then compute W_gas = −ΔU = −(f/2)nR(T₂ − T₁). Compare both to the table.
- With Q = 0 in every trial, the first law gives ΔU = −W_gas exactly. Explain, in terms of energy conservation, why an expanding gas that does positive work must cool down when it can't draw in heat.
5 · Extend
- An aerosol spray can feels cold as gas rushes out and expands rapidly — too fast to exchange much heat with the surroundings. Explain why this is a real-world (if imperfect) example of adiabatic cooling.
- Compare your final temperatures here to what isothermal-compression's reverse (an isothermal expansion) would give for the same volume change: isothermal keeps T constant, but this adiabatic case doesn't. Why does removing the heat-exchange assumption change the outcome?
The Physics Behind This Experiment
Adiabatic Process
With no heat exchanged (Q = 0), the first law reduces to ΔU = −W_gas: an expanding gas can only do work by spending its own internal energy, so it must cool. Pressure and volume follow P·V^γ = constant.